Research

研究主题:纳米催化与能源转化 (Nanocatalysis and Energy conversion)

我们研究目标是基于无机合成化学设计和合成新型的无机纳米结构,探索其在能源存储与转化领域的应用,揭示纳米结构组分、形貌及结构缺陷与性能之间的内在关系,开发先进的水系锌离子电池和光/电催化材料。

Our research goal is designing and synthesizing new nanostructures based on inorganic synthesis chemistry, exploring their potential applications in the field of energy storage and transformation, demonstrating the relationships between composition, morphology and structure defects of nanostructures and performances, and developing advanced aqueous Zn-ion batteries and (photo)electrocatalysis materials. 

水系锌离子电池 (Aqueous zinc-ion battery)

水系锌离子电池因兼具高安全性、低成本与环境友好等优势,在大规模储能及可穿戴设备等领域展现出广阔的应用前景。本团队聚焦于锌负极界面稳定性的关键科学问题,围绕负极/电解液界面反应行为调控,系统探索水凝胶电解液、电解质添加剂及负极界面层等多维度协同优化策略。针对锌负极在沉积/剥离过程中易出现的枝晶生长、析氢反应及表面腐蚀等副反应,研究通过构建兼具高离子电导率与良好机械柔性的水凝胶电解液体系,引入功能性添加剂调控锌离子溶剂化结构及界面电场分布,并设计人工界面层实现均匀的锌沉积形貌与界面化学环境优化。通过多策略耦合,旨在实现锌负极界面反应的可控性与可逆性提升,为构建长循环寿命、高安全性的水系锌离子电池提供理论依据与技术支撑。

Aqueous Zn-ion battery, characterized by high safety, low cost, and environmental friendliness, exhibit broad application prospects in fields such as large-scale energy storage and wearable devices. Our research team focuses on the key scientific issue of Zn anode interface stability, systematically exploring multidimensional synergistic optimization strategies, including hydrogel electrolytes, electrolyte additives, and artificial anode interfacial layers, to regulate the interfacial reaction behavior at the anode/electrolyte interface. To address the side reactions that readily occur during Zn plating/stripping, such as dendrite growth, hydrogen evolution, and surface corrosion, we develop hydrogel electrolyte systems that combine high ionic conductivity with good mechanical flexibility, introduces functional additives to modulate the solvation structure of zinc ions and the interfacial electric field distribution, and designs artificial interfacial layers to achieve uniform Zn deposition morphology and optimized interfacial chemical environments. By coupling these multiple strategies, this work aims to enhance the controllability and reversibility of the Zn anode interfacial reactions, thereby providing theoretical foundations and technical support for the development of long-cycle-life and high-safety aqueous Zn-ion batteries.

电催化 (Electrocatalysis)

本团队致力于研究界面电催化与新型电化学能源体系,围绕氧还原反应ORR)、氧析出反应OER)、硝酸根还原反应NORR及CN耦合等关键反应,开展催化材料设计、界面微环境构筑与反应机制解析。通过发展单原子催化剂、缺陷工程材料、异质结构电极及功能凝胶电解质/界面材料等,结合原位拉曼、原位红外等先进表征技术与理论计算,揭示反应中间体演化、表面重构及局域水/离子环境对催化性能的影响规律。同时,面向金属–空气电池、水分解及电催化耦合小分子转化体系,探索多反应协同、多界面调控和储能–催化一体化新路径,服务绿色能源转化与可持续化学品制造。

Our group focuses on interfacial electrocatalysis and emerging electrochemical energy systems, with research centered on key reactions including the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), nitrate reduction reaction (NORR), and C–N coupling. We conduct systematic studies on catalyst design, interfacial microenvironment engineering, and reaction mechanism elucidation. By developing advanced materials such as single-atom catalysts, defect-engineered nanomaterials, heterostructured electrodes, and functional gel electrolytes/interfacial materials, and integrating in situ Raman and infrared spectroscopies with theoretical simulations, we aim to uncover the evolution of reaction intermediates, surface reconstruction processes, and the role of local water/ion environments in governing catalytic performance. Furthermore, targeting metal–air batteries, water splitting, and electrocatalytic small-molecule coupling systems, we explore multi-reaction synergy, multi-interface regulation, and integrated energy storage–catalysis platforms, with the goal of advancing sustainable energy conversion and green chemical manufacturing.

光催化 (photocatalysis)

光催化技术利用半导体材料将太阳能转化为化学能,从而解决能源和环境问题。本团队致力于研究直接转化反应(N2还原为NH3、CO2还原为CO和CH4等、O2还原为H2O2以及H2O氧化为H2O2)和偶联转化反应(C–C偶联和C–N偶联)。针对光催化体系中载流子分离效率低、表面反应动力学迟缓等关键问题,我们发展了多种光活性增强策略,如缺陷工程、表面工程和异质结工程等,系统探究了光催化性能提升机制,为高附加值产物的绿色合成提供了新的科学依据与创新思路。

Photocatalytic technologies use semiconductors to convert solar energy into chemical energy for addressing energy and environmental challenges. Our group focuses on both direct and coupling conversion reactions. The direct conversion reactions include N2 reduction to NH3, CO2 reduction to CO and CH4, etc, O2 reduction to H2O2, and H2O oxidation to H2O2. Furthermore, the coupling conversion pathways encompass both C–C and C–N coupling reactions. To address key challenges in photocatalytic systems, such as low charge carrier separation efficiency and sluggish surface reaction kinetics, various strategies, such as defect engineering, surface engineering, and heterojunction engineering, have been proposed for semiconductors to improve their photoactivity. Through these approaches, we systematically investigated the mechanisms responsible for improved photocatalytic performance, thereby providing new scientific insights and innovative approaches for the green synthesis of high-value-added products.


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